asymmetric olefin metathesis

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Chapter 4. Asymmetric Ring-Closing Metathesis with Ruthenium Alkylidenes. Bearing Chiral, Monodentate N-Heterocyclic Carbene Ligands. Introduction. Asymmetric olefin metathesis does not seem possible at first glance, because no sp3-hybridized carbons are formed during a metathesis reaction. Instead of creating a.
J Am Chem Soc. 2003 Oct 15;125(41):12502-8. Chiral Ru-based complexes for asymmetric olefin metathesis: enhancement of catalyst activity through steric and electronic modifications. Van Veldhuizen JJ(1), Gillingham DG, Garber SB, Kataoka O, Hoveyda AH. Author information: (1)Department of Chemistry, Merkert
Chemistry. 2001 Mar 2;7(5):945-50. Catalytic asymmetric olefin metathesis. Hoveyda AH(1), Schrock RR. Author information: (1)Department of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, MA 02467, USA. This paper provides a survey of the first examples of efficient catalytic
23.02.2001 -
Abstract. Catalytic asymmetric ring-opening metathesis (AROM) provides an efficient method for the synthesis of a variety of optically enriched small organic molecules that cannot be easily prepared by alternative methods. The development of Mo-catalyzed AROM transformations that occur in tandem with ring-closing

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